scholarly journals The reaction of H8Si8O12 with a chromium oxide surface: a model for stainless steel surface modification

Author(s):  
J. N. Greeley ◽  
S. Lee ◽  
M. M. Banaszak Holl
1993 ◽  
Vol 140 (6) ◽  
pp. 1691-1699 ◽  
Author(s):  
Tadahiro Ohmi ◽  
Atsushi Ohki ◽  
Masakazu Nakamura ◽  
Koji Kawada ◽  
Tsuyoshi Watanabe ◽  
...  

ChemInform ◽  
2010 ◽  
Vol 24 (42) ◽  
pp. no-no
Author(s):  
T. OHMI ◽  
A. OHKI ◽  
M. NAKAMURA ◽  
K. KAWADA ◽  
T. WATANABE ◽  
...  

2002 ◽  
Vol 09 (01) ◽  
pp. 285-291 ◽  
Author(s):  
SANGWOON MOON ◽  
BOKLAE CHO ◽  
SUKMIN CHUNG ◽  
CHONGDO PARK ◽  
KIJEONG KIM ◽  
...  

We investigated the various oxidation conditions of stainless-steel surface using synchrotron radiation photoemission spectroscopy. Stainless-steel samples are oxidized at 450–550°C in various oxygen partial pressures. Increasing the annealing temperature from 450°C to 550°C, the trivalent chromium concentration in the surface increased and iron oxides decreased. The PES spectra from stainless steels oxidized at 550°C show that there exists the critical oxygen partial pressure, [Formula: see text] Torr. Below this critical pressure, the oxide formed mainly consists of chromium oxide, while the oxide formed mainly consists of iron oxide above the critical pressure. The oxidation behavior is in good agreement with the Ellingham diagram (a free-energy/temperature diagram).


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